Publikationen der AG Polarz



  • J. Bahner, L. Dobler, M. Frisch, L. Vogelsang, H. Cölfen, S. Polarz (2021): Direction-Dependent Properties in Inverted Carbon Nitride Colloidal Glasses with Gradient PorosityChemRxiv
  • J. Bahner, N. Hug, S. Polarz (2021): Anisotropic Magnetism in Gradient Porous Carbon Composite AerogelsCarbon Composite Aerogels.C 2021, 7, 22
  • M. L. Frisch, S. Polarz (2021): Molecular fusion of surfactant and Lewis-acid properties for attacking dirt by catalytic bond cleavageSci Rep 11, 5131 (2021)
  • N. Klinkenberg, S. Kraft, S. Polarz (2021): Great Location: About Effects of Surface Bound Neighboring Groups for Passive and Active Fine-Tuning of CO2 Adsorption Properties in Model Carbon Capture MaterialsAdv. Mater. 2021, 33, 2007734
    DOI: 2021
  • S. Bitter, M. Schilling, J. P. Brahm, S. Polarz, R. F. Winter (2021): Voltammetry as a Tool to Monitor the Aggregation Behavior of a Zwitterionic Ferrocene SurfactantLangmuir 2021, 37, 14, 4183–4191
  • S. Bitter, M. Schlötter M. Schilling R. Winter S. Polarz (2021): Ferro-Self-Assembly: Magnetic and Electrochemical Adaptation of a Multiresponsive Zwitterionic Metalloamphiphile Showing a Shape-Hysteresis EffectChem. Sci., 2021, 12, 270-281
    DOI: DOI: 10.1039/D0SC05249C
  • S. Theiss, M. Voggel, H. Kuper, M. Hoermann, U. Krings, P. Baum, J. A. Becker, V. Wittmann, S. Polarz (2021): Ligand-Programmed Consecutive Symmetry Break(s) in Nanoparticle Based Materials Showing Emergent Phenomena: Transitioning from Sixfold to Threefold Symmetry in Anisotropic ZnO ColloidsAdv. Funct. Mater. 2021, 31, 2009104
  • Y. Krysiak, M. Maslyk, B. Nádia Silva, S. Plana-Ruiz, H. M. Moura, E. O. Munsignatti, V. S. Vaiss, U. Kolb, W. Tremel, L. Palatinus, A. A. Leitão, B. Marler, H. O. Pastore (2021): The Elusive Structure of Magadiite, Solved by 3D Electron Diffraction and Model BuildingChem. Mater. 2021, 33, 9, 3207–3219
  • B. Marler, Y. Krysiak, U. Kolb, C. Grafweg, H. Giesa (2020): Two new members of the Silica-X family of materials: RUB-5, a silica zeolite with a very high framework density and RUB-6, a hydrous layer silicateMicroporous and Mesoporous Materials, 2020 Vol. 296, , 109981
  • D. Kollofrath, M. Geppert, S. Polarz (2020): Copolymerization of Mesoporous Styrene‐Bridged Organosilica Nanoparticles with Functional Monomers for the Stimuli‐Responsive Remediation of WaterChemSusChem
    DOI: 020
  • Fillafer, N., Seewald, T., Schmidt-Mende, L., Polarz, S. (2020): Interfacial charge transfer processes in 2D and 3D semiconducting hybrid perovskites: azobenzene as photoswitchable ligandBeilstein J. Nanotech., 11, 466-479
    DOI: 10.3762/bjnano.11.38
  • H. Bronner, A. K. Holzer, A. Finke, M. Kunkel, A. Marx, M. Leist, S. Polarz (2020): The influence of structural gradients in large pore organosilica materials on the capabilities for hosting cellular communitiesRSC Advances 10.29 (2020): 17327-17335
    DOI: 10.1039/D0RA00927J
  • Kunkel, M., Bitter, S., Sailer, F., Winter, R. F., Polarz, S. (2020): Aggregation‐Induced Improvement of Catalytic Activity by Inner‐Aggregate Electronic Communication of Metal‐Fullerene‐Based SurfactantsChem. Cat. Chem.
    DOI: 10.1002/cctc.202000412
  • Lanz, C., Schlötter, M., Klinkenberg, N., Besirske, P., Polarz, S., (2020): Stimuli‐Responsive Particle‐Based Amphiphiles as Active Colloids Prepared by Anisotropic Click ChemistryAngew. Chem. Int. Ed., 2020, 59, 8902-8906
    DOI: 10.1002/anie.202001423
  • M. A. Lange, Y. Krysiak, J. Hartmann, G. Dewald, G. Cerretti, M. N. Tahir, M. Panthöfer, B. Barton, T. Reich, W. G. Zeier, M. Mondeshki, U. Kolb, W. Tremel (2020): Solid State Fluorination on the Minute Scale: Synthesis of WO3−xFx with PhotocatalyticAdv. Funct. Mater. 2020, 30, 1909051
  • S. Plana-Ruiza, Y. Krysiak, J. Portillo, E. Alig, S. Estradé, F. Peiró, U. Kolb (2020): Fast-ADT: A fast and automated electron diffraction tomography setup for structure determination and refinement
  • T. Herzog, N. Weitzel, S. Polarz (2020): Oxygen vacancy injection-induced resistive switching in combined mobile and static gradient doped tin oxide nanorodsNanoscale 12 (35), 18322-18332
    DOI: 10.1039/D0NR03734F
  • Y. Krysiak, B. Marler, B. Barton, S. Plana-Ruiz, H. Gies, R. B. Nederf, U. Kolb (2020): New zeolite-like RUB-5 and its related hydrous layer silicate RUB-6 structurally characterized by electron microscopyIUCrJ, 2020, Vol 7, 3, 522-534
  • Bahner, J., Klinkenberg, N., Frisch, M., Brauchle, L., Polarz, S. (2019): Creating Directionality in Nanoporous Carbon Materials: Adjustable Combinations of Structural and Chemical GradientsAdv. Funct. Mater., 29, 1904058
    DOI: 10.1002/adfm.201904058
  • Donner, A., Trepka, B., Theiss, S., Immler, F., Traber, J., Polarz, S. (2019): NCH-Metallosurfactants as Active Polymerization CatalystsLangmuir, 35, 16514-16520
    DOI: 10.1021/acs.langmuir.9b02152
  • Kalb, J., Folger, A., Zimmermann, E., Gerigk, M., Trepka, B., Scheu, C., Polarz, S., Schmidt-Mende, L. (2019): Controlling the density of hydrothermally grown rutile TiO2 nanorods on anatase TiO2 filmsSurf. Interfaces, 15, 141-147
    DOI: 10.1016/j.surfin.2019.02.010
  • Klinkenberg, N., Klaiber, A., Müler, M., Polarz, S. (2019): Versatile surface modification of aerogels by click chemistry as an approach to generate model systems for CO2 adsorption features in amine-containing organosilicaMicroporous and Mesoporous Mater., 294, 109879
    DOI: 10.1016/j.micromeso.2019.109879
  • Kunkel, M., Sutter, S., Polarz, S. (2019): Molecular Semiconductor Surfactants with Fullerenol Head and Colored Tails for Photoconversion of Carbon DioxideAngew. Chem. Int. Ed., 58, 15620-15625
    DOI: 10.1002/anie.201905410
  • Kunkel, M., Sutter, S., Polarz, S. (2019): Molekulare Halbleiter‐Tenside mit Fullerenol‐Kopfgruppe und Farbstoffketten für die photokatalytische Umwandlung von KohlenstoffdioxidAngew. Chem., 131, 15766-15771
    DOI: 10.1002/ange.201905410
  • Kunkel, M., Polarz, S. (2019): Easy, efficient and versatile one-pot synthesis of Janus-type-substituted fullerenolsBeilstein J. Org. Chem., 15, 901-905
    DOI: 10.3762/bjoc.15.87
  • Schertel, L., Wimmer, I., Besirske, P., Aegerter, C. M., Maret, G., Polarz, S., Aubry, G. J. (2019): Tunable high-index photonic glassesPhys. Rev. Mater., 3, 015203
    DOI: 10.1103/PhysRevMaterials.3.015203
  • Sutter, S., Trepka, B., Siroky, S., Hagedorn, K., Theiss, S., Baum, P., Polarz, S. (2019): Light-Triggered Boost of Activity of Catalytic Bola-Type Surfactants by a Plasmonic Metal-Support Interaction EffectACS Appl. Mater. Interfaces, 11, 15936-15944
    DOI: 10.1021/acsami.9b03727
  • Theiss, S., Voggel, M., Schlötter, M., Sutter, S., Stöckl, M. T., Polarz, S., (2019): Tolerance in superstructures formed from high-quality colloidal ZnO nanoparticles with hexagonal cross-sectionCryst. Eng. Comm., 21, 5137-5144
    DOI: 10.1039/c9ce00811j
  • Trepka, B., Emminger, Y. H., Schneider, N., Schlotter, M., Theiss, S., Wimmer, I., Fonin, M., Polarz, S. (2019): Sacrificial Templating: A Route to Europium-II Oxide (EuO) Particles with Arbitrary Shape Prepared Indirectly by Hostile TakeoverCryst. Growth Des., 19, 4234-4238
    DOI: 10.1021/acs.cgd.9b00443
  • U. Kolb, Y. Krysiak, S. Plana-Ruiz (2019): Automated electron diffraction tomography - Development and applicationsActa Cryst. (2019). B75, 463-474
  • Bitter, S., Kunkel, M., Burkart, L., Mang, A., Winter, R. F., Polarz, S. (2018): Organometallic, Nonclassical Surfactant with Gemini Design Comprising pi-Conjugated Constituents Ready for ModificationACS Omega, 3, 8854-8864
    DOI: 10.1021/acsomega.8b01405
  • Boldt, K., Polarz, S. (2018): Formabhängige Eigenschaften und kooperative EffekteNachrichten aus der Chemie, 66, 1042-1046
    DOI: 10.1002/nadc.20184073205
  • D. Bowden, Y. Krysiak, L. Palatinus, D. Tsivoulas, S. Plana-Ruiz, E. Sarakinou, U. Kolb, D. Stewart, M. Preuss (2018): A high-strength silicide phase in a stainless steel alloy designed for wear-resistant applicationsNat Commun 9, 1374 (2018).
  • Kalb, J., Dorman, J. A., Folger, A., Gerigk, M., Knittel, V., Plüisch, C. S., Trepka, B., Lehr, D., Chua, E., Goodge, B. H., Wittemann, A., Polarz, S., Schmidt-Mende, L. (2018): Influence of substrates and rutile seed layers on the assembly of hydrothermally grown rutile TiO2 nanorod arrays
  • Klaiber, A., Kollek, T., Cardinal, S., Hug, N., Drechsler, M., Polarz, S. (2018): Electron Transfer in Self-Assembled Micelles Built by Conductive Polyoxometalate-Surfactants Showing Battery-Like BehaviorAdv. Mater. Interfaces, 5, 1701430
    DOI: 10.1002/admi.201701430
  • Kunkel, M., Schildknecht, S., Boldt, K., Zeyffert, L., Schleheck, D., Leist, M., Polarz, S. (2018): Increasing the Resistance of Living Cells against Oxidative Stress by Nonnatural Surfactants as Membrane GuardsACS Appl. Mater. Interfaces, 10, 23638-23646
    DOI: 10.1021/acsami.8b07032
  • Pivtsov, A., Wessig, M., Klovak, V., Polarz, S., Drescher, M. (2018): Localization of Guest Molecules in Nanopores by Pulsed EPR SpectroscopyJ. Phys. Chem. C, 122, 5376-5384
    DOI: 10.1021/acs.jpcc.7b10758
  • Trepka, B., Erler, P., Selzer, S., Kollek, T., Boldt, K., Fonin, M., Nowak, U., Wolf, D., Lubk, A., Polarz, S. (2018): Nanomorphology Effects in Semiconductors with Native Ferromagnetism: Hierarchical Europium (II) Oxide Tubes Prepared via a Topotactic Nanostructure TransitionAdv. Mater., 30, 1703612
    DOI: 10.1002/adma.201703612
  • Trepka, B., Stiegeler, J., Wimmer, I., Fonin, M., Polarz, S. (2018): EurOgels : A ferromagnetic semiconductor with a porous structure prepared via the assembly of hybrid nanorodsNanoscale, 10, 19272-19276
    DOI: 10.1039/c8nr06536e
  • Voggel, M., Meinusch, R. M., Siewert, V., Kunkel, M., Wittmann, V., Polarz, S. (2018): Sweet surfactants: packing parameter-invariant amphiphiles as emulsifiers and capping agents for morphology control of inorganic particlesSoft Matter., 14, 7214-7227
    DOI: 10.1039/c8sm01091a
  • Y. Krysiak, B. Barton, B. Marler, R. B. Neder, U. Kolb (2018): Ab initio structure determination and quantitative disorder analysis on nanoparticles by electron diffraction tomographyActa Cryst. (2018). A74, 93-101
  • Aubry, G. J., Schertel, L., Chen, M. D., Weyer, H., Aegerter, C. M., Polarz, S., Cölfen, H., Maret, G. (2017): Resonant transport and near-field effects in photonic glassesPhys. Rev. A, 96, 043871
    DOI: 10.1103/PhysRevA.96.043871
  • B. K. Heep, K. S. Weldert, Y. Krysiak, T. W. Day, W. G. Zeier, U. Kolb, G. J. Snyder, W.Tremel (2017): High Electron Mobility and Disorder Induced by Silver Ion Migration Lead to Good Thermoelectric Performance in the Argyrodite Ag8SiSe6Chem. Mater. 2017, 29, 11, 4833–4839
  • Bauer, T., Voggenreiter, M., Xu, T., Wahler, T., Agel, F., Pohako-Esko, K., Schulz, P., Dopper, T., Gorling, A., Polarz, S., Wasserscheid, P., Libuda, J. (2017): ZnO Nanoparticle Formation from the Molecular Precursor [MeZnOtBu]4 by Ozone Treatment in Ionic Liquids: in-situ Vibrational Spectroscopy in an Ultrahigh Vacuum EnvironmentZ. Anorg. Allg. Chem., 643, 31-40
    DOI: 10.1002/zaac.201600345
  • Birkhold, S. T., Zimmermann, E., Kollek, T., Wurmbrand, D., Polarz, S., Schmidt-Mende, L. (2017): Impact of Crystal Surface on Photoexcited States in Organic-Inorganic PerovskitesAdv. Funct. Mater., 27, 1604995
    DOI: 10.1002/adfm.201604995
  • Chen, M., Hagedorn, K., Cölfen, H., Polarz, S. (2017): Functional Gradient Inverse Opal Carbon Monoliths with Directional and Multinary PorosityAdv. Mater., 29, 1603356
    DOI: 10.1002/adma.201603356
  • Donner, A., Hagedorn, K., Mattes, L., Drechsler, M., Polarz, S. (2017): Hybrid Surfactants with N-Heterocyclic Carbene Heads as a Multifunctional Platform for Interfacial CatalysisChem. Eur. J., 23, 18129-18133
    DOI: 10.1002/chem.201703902
  • Gerigk, M., Bahner, J., Kollek, T., Helfrich, S., Rosenberg, R., Colfen, H., Polarz, S. (2017): Order and Defects in Ceramic Semiconductor Nanoparticle Superstructures as a Function of Polydispersity and Aspect RatioPart. Part. Syst. Char., 34, 1600215
    DOI: 10.1002/ppsc.201600215
  • H. Zhao, A. Bodach, M. Heine, Y. Krysiak, J. Glinnemann, E. Alig, L. Fink, M. U. Schmidt (2017): 4-Cyanopyridine, a versatile mono- and bidentate ligand. Crystal structures of related coordination polymers determined by X-ray powder diffractionCrystEngComm, 2017,19, 2216-2228
  • H. Zhao, Y. Krysiak, K. Hoffmann, B. Barton, L. Molina-Luna, R. B. Neder, H. Kleebe, T. M. Gesing, H. Schneider, R. X. Fischer, U. Kolb (2017): Elucidating structural order and disorder phenomena in mullite-type Al4B2O9 by automated electron diffraction tomographyJournal of Solid State Chemistry, 2017, 249, 114-123.
  • Hagedorn, K., Bahnmüller, U., Schachtschneider, A., Frei, M., Li, W., Schmedt Auf der Gunne, J., Polarz, S. (2017): Nonequilibrium Catalyst Materials Stabilized by the Aerogel Effect: Solvent Free and Continuous Synthesis of Gamma-Alumina with Hierarchical PorosityACS Appl. Mater. Interfaces, 9, 11599-11608
    DOI: 10.1021/acsami.6b16721
  • Hermann, S., Wessig, M., Kollofrath, D., Gerigk, M., Hagedorn, K., Odendal, J. A., Hagner, M., Drechsler, M., Erler, P., Fonin, M., Maret, G., Polarz, S. (2017): Magneto-Adaptive Surfactants Showing Anti-Curie Behavior and Tunable Surface Tension as Porogens for Mesoporous Particles with 12-Fold SymmetryAngew. Chem. Int. Ed., 56, 5475-5479
    DOI: 10.1002/anie.201612416
  • Jana, A., Scheer, E., Polarz, S. (2017): Synthesis of graphene–transition metal oxide hybrid nanoparticles and their application in various fieldsBeilstein J. Nanotechnol., 8, 688-714
    DOI: 10.3762/bjnano.8.74
  • Kollek, T., Polarz, S. (2017): Facet-controlled preparation of hybrid perovskite microcrystals in the gas phase and the remarkable effect on optoelectronic propertiesCryst. Eng. Comm., 19, 4615-4621
    DOI: 10.1039/c7ce00839b
  • Kollek, T., Wurmbrand, D., Birkhold, S. T., Zimmermann, E., Kalb, J., Schmidt-Mende, L., Polarz, S. (2017): Thiophene-Functionalized Hybrid Perovskite Microrods and their Application in Photodetector Devices for Investigating Charge Transport Through Interfaces in Particle-Based MaterialsACS Appl. Mater. Interfaces, 9, 1077-1085
    DOI: 10.1021/acsami.6b12466
  • Spitzbarth, M., Scherer, A., Schachtschneider, A., Imming, P., Polarz, S., Drescher, M. (2017): Time-, spectral- and spatially resolved EPR spectroscopy enables simultaneous monitoring of diffusion of different guest molecules in nano-poresJ. Magn. Reson., 283, 45-51
    DOI: 10.1016/j.jmr.2017.08.008
  • Voepel, P., Seitz, C., Waack, J. M., Zahn, S., Leichtweiss, T., Zaichenko, A., Mollenhauer, D., Amenitsch, H., Voggenreiter, M., Polarz, S., Smarsly, B. M. (2017): Peering into the Mechanism of Low-Temperature Synthesis of Bronze-type TiOCryst. Growth Des., 17, 5586-5601
    DOI: 10.1021/acs.cgd.7b01231
  • Voggenreiter, M., Vopel, P., Smarsly, B., Polarz, S. (2017): Low Temperature Reaction of Molecular Zinc Oxide Precursors in Ionic Liquids Leading to Ionogel Nanoparticles with Shape AnisotropyZ. Anorg. ALlg. Chem., 643, 93-100
    DOI: 10.1002/zaac.201600341
  • Wessig, M., Spitzbarth, M., Klaiber, A., Drescher, M., Polarz, S. (2017): Negative and Positive Confinement Effects in Chiral Separation Chromatography Monitored with Molecular-Scale Precision by In-Situ Electron Paramagnetic Resonance TechniquesLangmuir, 33, 11968-11976
    DOI: 10.1021/acs.langmuir.7b02713
  • Feng, Y. Y., Kim, K. D., Nemitz, C. A., Kim, P., Pfadler, T., Gerigk, M., Polarz, S., Dorman, J. A., Weickert, J., Schmidt-Mende, L. (2016): Uniform Large-Area Free-Standing Silver Nanowire Arrays on Transparent Conducting SubstratesJ. Electrochem. Soc., 163, D447-D452
    DOI: 10.1149/2.1141608jes
  • Gehring, J. Trepka, B. Klinkenberg, N. Bronner, H. Schleheck, D. Polarz, S. (2016): Sunlight-Triggered Nanoparticle Synergy: Teamwork of Reactive Oxygen Species and Nitric Oxide Released from Mesoporous Organosilica with Advanced Antibacterial ActivityJ. Am. Chem. Soc., 138, 3076-3084
    DOI: 10.1021/jacs.5b12073
  • Hagedorn, K., Li, W. Y., Liang, Q. J., Dilger, S., Noebels, M., Wagner, M. R., Reparaz, J. S., Dollinger, A., Gunne, J. S. A. D., Dekorsy, T., Schmidt-Mende, L., Polarz, S. (2016): Catalytically Doped Semiconductors for Chemical Gas Sensing: Aerogel-Like Aluminum-Containing Zinc Oxide Materials Prepared in the Gas PhaseAdv. Funct. Mater., 26, 3424-3437
    DOI: 10.1002/adfm.201505355
  • Hu, H., Wong, K. K., Kollek, T., Hanusch, F., Polarz, S., Docampo, P., Schmidt-Mende, L. (2016): Highly Efficient Reproducible Perovskite Solar Cells Prepared by Low-Temperature ProcessingMolecules, 21, 542
    DOI: 10.3390/molecules21040542
  • Klaiber, A., Lanz, C., Landsmann, S., Gehring, J., Drechsler, M., Polarz, S. (2016): Maximizing Headgroup Repulsion: Hybrid Surfactants with Ultrahighly Charged Inorganic Heads and Their Unusual Self-AssemblyLangmuir, 32, 10920-10927
    DOI: 10.1021/acs.langmuir.6b02661
  • Klaiber, A., Polarz, S. (2016): Passing current through electrically conducting lyotropic liquid crystals and micelles assembled from hybrid surfactants with π-conjugated tail and polyoxometalate headACS Nano, 10, 10041-10048
    DOI: 10.1021/acsnano.6b04677
  • Kollek, T., Fischer, C., Gottker-Schnetmann, I., Polarz, S. (2016): Microwave Induced Crystallization of the Hybrid Perovskite CH3NH3PbI3 from a Supramolecular Single-Source PrecursorChem. Mater., 28, 4134-4138
    DOI: 10.1021/acs.chemmater.6b01263
  • M. B. Mesch, K. Bärwinkel, Y. Krysiak, C. Martineau, F. Taulelle, R. B. Neder, U. Kolb, J. Senker (2016): Solving the Hydrogen and Lithium Substructure of Poly(triazine imide)/LiCl Using NMR Crystallography
  • (2015): Multiple scale investigation of molecular diffusion inside functionalized porous hosts using a combination of magnetic resonance methodsPhys. Chem. Chem. Phys., 17, 15976-15988
    DOI: 10.1039/c5cp01369k
  • Chen, M., Cölfen, H., Polarz, S. (2015): Centrifugal Field-Induced Colloidal Assembly: From Chaos to OrderACS Nano, 9, 6944-6950
    DOI: 10.1021/acsnano.5b01116
  • Gehring, J., Schleheck, D., Trepka, B., Polarz, S. (2015): Mesoporous Organosilica Nanoparticles Containing Superacid and Click Functionalities Leading to Cooperativity in Biocidal CoatingsACS Appl. Mater. Interfaces, 7, 1021-1029
    DOI: 10.1021/am5083057
  • Gerigk, M., Ehrenreich, P., Wagner, M. R., Wimmer, I., Reparaz, J. S., Torres, C. M. S., Schmidt-Mende, L., Polarz, S. (2015): Nanoparticle shape anisotropy and photoluminescence properties: Europium containing ZnO as a Model CaseNanoscale, 7, 16969-16982
    DOI: 10.1039/c5nr02550h
  • I. Andrusenko, Y. Krysiak, E. Mugnaioli, T. E. Gorelik, D. Nihtianova, U. Kolb (2015): Structural insights into M2O-Al2O3-WO3 (M = Na, K) system by electron diffraction tomographyActa Cryst. (2015). B71, 349-357
  • Kollek, T. Gruber, D. Gehring, J. Zimmermann, E. Schmidt-Mende, L. Polarz, S. (2015): Porous and shape-anisotropic single crystals of the semiconductor perovskite CH3NH3PbI3 from a single-source precursorAngew. Chem. Int. Ed., 54, 1341-1346
    DOI: 10.1002/anie.201408713
  • Kollek, T., Gruber, D., Gehring, J., Zimmermann, E., Schmidt‐Mende, L., Polarz, S. (2015): Poröse und formanisotrope Einkristalle des Halbleiter‐Perowskits CH3NH3PbI3 aus einer neuen Single‐Source‐VorstufeAngew. Chem., 127, 1357-1362
    DOI: 10.1002/ange.201408713
  • Lehr, D., Wagner, M. R., Flock, J., Reparaz, J. S., Torres, C. M. S., Klaiber, A., Dekorsy, T., Polarz, S. (2015): Correction: A single-source precursor route to anisotropic halogen-doped zinc oxide particles as a promising candidate for new transparent conducting oxide materialsBeilstein J. Nanotechnol., 6, 2330-2331
    DOI: 10.3762/bjnano.6.239
  • Luka, M., Karreman, S., Polarz, S. (2015): Plug and play synthesis of an organic/inorganic hybrid electrode with adjustable porosity: redox-active organosilica confined in mesoporous carbonJ. Mater. Chem. A, 3, 22017-22020
    DOI: 10.1039/c5ta06885a
  • Luka, M., Polarz, S. (2015): Wiring functional groups in mesoporous organosilica materialsJ. Mater. Chem. C, 3, 2195-2203
    DOI: 10.1039/c4tc02746a
  • Polarz, S., Odendal, J. A., Hermann, S., Klaiber, A. (2015): Amphiphilic hybrids containing inorganic constituent: More than soapCurr. Opin. Colloid Interface Sci., 20, 151-160
    DOI: 10.1016/j.cocis.2015.07.006
  • Schachtschneider, A., Wessig, M., Spitzbarth, M., Donner, A., Fischer, C., Drescher, M., Polarz, S. (2015): Directional materials—nanoporous organosilica monoliths with multiple gradients prepared using click chemistryAngew. Chem. Int. Ed., 54, 10465-10469
    DOI: 10.1002/anie.201502878
  • Spitzbarth, M., Wessig, M., Lemke, T., Schachtschneider, A., Polarz, S., Drescher, M. (2015): Simultaneous Monitoring of Macroscopic and Microscopic Diffusion of Guest Molecules in Silica and Organosilica Aerogels by Spatially and Time-Resolved Electron Paramagnetic Resonance SpectroscopyJ. Phys. Chem. C, 119, 17474-17479
    DOI: 10.1021/acs.jpcc.5b05743
  • Dilger, S. Wessig, M. Wagner, M. R. Reparaz, J. S. Sotomayor Torres, C. M. Liang, Q. Dekorsy, T. Polarz, S. (2014): Nanoarchitecture Effects on Persistent Room Temperature Photoconductivity and Thermal Conductivity in Ceramic Semiconductors: Mesoporous, Yolk-Shell, and Hollow ZnO SpheresCryst. Growth Des., 14, 4593-4601
    DOI: 10.1021/cg500680g
  • Dollinger, A Stolch, L. Luo, Y. Beck, M. Strobel, C. H. Hagner, M. Dilger, S Bein, M. Polarz, S. Gantefoer, G. F. Kim, Y.-D. Proch, S. (2014): Size-selected gold clusters on porous titania as the most “gold-efficient” heterogeneous catalystsPhys. Chem. Chem. Phys, 16, 11017-11023
    DOI: 10.1039/C4CP00597J
  • Gehring, J. Schleheck, D. Luka, M. Polarz, S. (2014): Aerosol-synthesis of mesoporous organosilica nanoparticles with highly reactive, superacidic surfaces comprising sulfonic acid entitiesAdv. Funct. Mater., 24, 1140-1150
    DOI: 10.1002/adfm.201302330
  • Lehr, D. Großmann, D. Grünert, W. Polarz, S. (2014): “Dirty nanostructures”: aerosol-assisted synthesis of temperature stable mesoporous metal oxide semiconductor spheres comprising hierarchically assembled zinc oxide nanocrystals controlled via impuritiesNanoscale, 6, 1698-1706
    DOI: 10.1039/C3NR05007F
  • Lizandara-Pueyo, C., Dilger, S., Wagner, M. R., Gerigk, M., Hoffmann, A., Polarz, S. (2014): Li-doped ZnO nanorods with single-crystal quality - non-classical crystallization and self-assembly into mesoporous materialsCryst. Eng. Comm., 16, 1525-1531
    DOI: 10.1039/c3ce41670d
  • Polarz, S., Landsmann, S., Klaiber, A. (2014): Hybride Tensidsysteme mit anorganischen BestandteilenAngew. Chem., 126, 962-970
    DOI: 10.1002/ange.201303159
  • T. Bernert, B.Winkler, Y. Krysiak, L. Fink, M. Berger, E. Alig, L. Bayarjargal, V. Milman, L. Ehm∥, P. W. Stephens, N. Auner, H. Lerner (2014): Determination of the Crystal Structure of Hexaphenyldisilane from Powder Diffraction Data and Its Thermodynamic PropertiesCryst. Growth Des., 2014, 14, 6, 2937–2944
  • Y. Krysiak, L. Fink, T. Bernert, J. Glinnemann, M. Kapuscinski, H. Zhao, E. Alig, M. U. Schmidt (2014): Crystal Structures and Polymorphism of Nickel and Copper Coordination Polymers with Pyridine LigandsZeitschrift für anorganische und allgemeine Chemie, 2014, 640.
  • Chen, M. Cölfen, H. Polarz, S. (2013): The Effect of Centrifugal Force on the Assembly and Crystallization of Binary Colloidal Systems: Towards Structural GradientsZ. Naturforsch. B, 68, 103-110
    DOI: 10.5560/ZNB.2013-3001
  • Grünert, W. Gies, H. Muhler, M. Polarz, S. Lehmann, C. W. Großmann, D. van den Berg, M. Tkachenko, O. P. De Toni, A. Sinev, I. Bandyopadhyay, M. Narkhede, V. Dreier, A. Klementiev, K. V. Birkner, A. Löffler, E. (2013): Metal–supported catalysts encapsulated in mesoporous solids: Challenges and opportunities of a model conceptPhys. Status Solidi B, 250, 1081-1093
    DOI: 10.1002/pssb.201248454
  • Polarz, S. Bährle, C. Landsmann, S. Klaiber, A. (2013): Panoscopic Structures by Hierarchical Cascade Self-Assembly of Inorganic Surfactants with Magnetic Heads Containing Dysprosium IonsAngew. Chem. Int. Ed., 52, 13665-13670
    DOI: 10.1002/anie.201303565
  • Wessig, M. Drescher, M. Polarz, S. (2013): Probing Functional Group Specific Surface Interactions in Porous Solids Using ESR Spectroscopy as a Sensitive and Quantitative ToolJ. Phys. Chem. C, 117, 2805-2816
    DOI: 10.1021/jp310226f
  • Dilger, S. Lizandra-Pueyo, C. Krumm, M. Polarz, S. (2012): Hierarchical Zinc Oxide Materials with Multiple Porosity Prepared by Ultrafast Temperature Gradient Chemical Gas-Phase SynthesisAdv. Mater., 24, 543-548
    DOI: 10.1002/adma.201103557
  • Giner-Casares, J. J. Brezesinski, G. Mohwald, H. Landsmann, S. Polarz, S. (2012): Polyoxometalate Surfactants as Unique Molecules for Interfacial Self-AssemblyJ. Phys. Chem. Lett., 3, 322-326
    DOI: 10.1021/jz201588z
  • Krumm, M. Pawlitzek, F. Weickert, J. Schmidt-Mende, L. Polarz, S. (2012): Temperature-stable and optically transparent thin-film zinc oxide aerogel electrodes as model systems for 3D interpenetrating organic–inorganic heterojunction solar cells.ACS Appl. Mater. Interfaces, 12, 6522-6529
  • Landsmann, S. Luka, M. Polarz, S. (2012): Bolaform surfactants with polyoxometalate head groups and their assembly into ultra-small monolayer membrane vesiclesNat. Comm., 3, 1-6
    DOI: 10.1038/ncomms2321
  • Landsmann, S. Wessig, M. Schmid, M. Cölfen, H. Polarz, S. (2012): Intelligente anorganische Tenside: mehr als OberflächenspannungAng. Chem. Int. Ed., 51, 5995-5999
    DOI: 10.1002/ange.201200139
  • Lehr, D. Luka, M. Wagner, M. R. Bulger, M. Hoffmann, A. Polarz, S. (2012): Band-Gap Engineering of Zinc Oxide Colloids via Lattice Substitution with Sulfur Leading to Materials with Advanced Properties for Optical Applications Like Full Inorganic UV ProtectionChem. Mater., 24, 1771-1778
    DOI: 10.1021/cm300239q
  • Lizandara-Pueyo, C. Morant-Minana, M. C. Wessig, M. Krumm, M. Mecking, S. Polarz, S. (2012): Biomimetic crystallization of anisotropic zinc oxide nanoparticles in the homogeneous Phase : shape control by surface additives applied under thermodynamic or kinetic controlRSC Adv., 2, 5298-5306
    DOI: 10.1039/c2ra20343j
  • (2011): Chemical architectonics for complex inorganic materialsBioinorg. React. Mech., 7, 27-64
    DOI: 10.1515/BIRM.2011.002
  • Lizandara‐Pueyo, C. Siroky, S. Wagner, M. R Hoffmann, A. Reparaz, J. S. Lehmann, M. Polarz, S. (2011): Shape Anisotropy Influencing Functional Properties: Trigonal Prismatic ZnO Nanoparticles as an ExampleAdv. Funct. Mater., 21, 295-304
    DOI: 10.1002/adfm.201000997
  • Polarz, S. Jeremias, F. Haunz, U. (2011): Materials Surgery - Reactivity Differences of Organic Groups in HybridsAdv. Funct. Mater, 21, 2953-2959
    DOI: 10.1002/adfm.201100802
  • Dilger, S. Hintze, C. Krumm, M. Lizandara-Pueyo, C. Deeb, S. Proch, S. Polarz, S. (2010): Gas phase synthesis of titania with aerogel character and its application as a support in oxidation catalysisJ. Mater. Chem., 20, 10032-10040
    DOI: 10.1039/c0jm00769b
  • Dreher, M. A. Krumm, M. Lizandara-Pueyo, C. Polarz, S. (2010): Chromium containing zinc oxide materials from organobimetallic precursorsDalton Trans, 39, 2232-2238
    DOI: 10.1039/b916253b
  • Krumm, M. Lizandra-Pueyo, C. Polarz, S. (2010): Monolithic Zinc Oxide Aerogels from Organometallic Sol-Gel PrecursorsChem. Mater., 22, 5129-5136
    DOI: 10.1021/cm1006907
  • Kuschel, A. Drescher, M. Kuschel, T. Polarz, S. (2010): Bifunctional Mesoporous Organosilica Materials and Their Application in Catalysis: Cooperative Effects or Not?Chem. Mater., 22, 1472-1482
    DOI: 10.1021/cm903412e
  • Kuschel, A. Luka, M. Wessig, M. Drescher, M. Fonin, M. Kiliani, G. Polarz, S. (2010): Organic Ligands Made Porous: Magnetic and Catalytic Properties of Transition Metals Coordinated to the Surfaces of Mesoporous OrganosilicaAdv. Funct. Mater., 20, 1133-1143
    DOI: 10.1002/adfm.200902056
  • Kuschel, A. Polarz, S. (2010): Effects of Primary and Secondary Surface Groups in Enantioselective Catalysis Using Nanoporous Materials with Chiral WallsJ. Am. Chem. Soc., 132, 6558-6565
    DOI: 10.1021/ja1017706
  • Lizandara Pueyo, C. Siroky, S. Landsmann, S. van den Berg, M. WE Wagner, M. R. Reparaz, J. S. Hoffmann, A. Polarz, S. (2010): Molecular precursor route to a metastable form of Zinc OxideChem. Mater., 22, 4263-4270
    DOI: 10.1021/cm101240n
  • Mascotto, S. Wallacher, D. Kuschel, A. Polarz, S. Zickler, G. A. Timmann, A. Smarsly, B. M. (2010): Adsorption in periodically ordered mesoporous organosilica materials studied by in situ small-angle X-ray scattering and small-angle neutron scatteringLangmuir, 26, 6583-6592
    DOI: 10.1021/la903934r
  • Polarz, S. Pueyo, C. L. Krumm, M. (2010): The molecular path to inorganic materials - Zinc oxide and beyondInorg. Chim. Acta, 363, 4148-4157
    DOI: 10.1016/j.ica.2010.06.053
  • Polarz, S. Volker, B. Jeremias, F. (2010): Metathesis catalysts in confining reaction fields-confinement effects vs. surface effectsDalton Trans., 39, 577-584
    DOI: 10.1039/b911795b
  • Rauch, C. Gehlhoff, W. Wagner, M. R. Malguth, E. Callsen, G. Kirste, R. Salameh, B. Hoffmann, A. Polarz, S. Aksu, Y. Driess, M. (2010): Lithium related deep and shallow acceptors in Li-doped ZnO nanocrystalJ. Appl. Phys., 107, 024311
    DOI: 10.1063/1.3275889
  • Polarz, S. Orlov, A. Hoffmann, A. Wagner, M. R. Rauch, C. Kirste, R. Gehlhoff, W. Aksu, Y. Driess, M. van den Berg, M. W. E. (2009): A Systematic Study on Zinc Oxide Materials Containing Group I Metals (Li, Na, K)-Synthesis from Organometallic Precursors, Characterization, and PropertiesChem. Mater., 21, 3889-3897
    DOI: 10.1021/cm9014223
  • Van den Berg, M. WE Polarz, S. Tkachenko, O. P. Kähler, K. Muhler, M. Grünert, W. (2009): Dynamical Changes in the Cu-ZnOx Interaction Observed in a Model Methanol Synthesis CatalystCatal. Letters, 128, 49-56
    DOI: 10.1007/s10562-008-9746-4
  • Kuschel, A. Polarz, S. (2008): Organosilica materials with bridging phenyl derivatives incorporated into the surfaces of mesoporous solidsAdv. Funct. Mater., 18, 1272-1280
    DOI: 10.1002/adfm.200701252
  • Kuschel, A. Sievers, H. Polarz, S. (2008): Amino Acid Silica Hybrid Materials with Mesoporous Structure and Enantiopure SurfacesAngew. Chem. Int. Ed., 47, 9513-9517
    DOI: 10.1002/anie.200803405
  • Lizandara-Pueyo, C. van den Berg, M. W. E. De Toni, A. Goes, T. Polarz, S. (2008): Nucleation and Growth of ZnO in Organic Solvents - an in Situ StudyJ. Am. Chem. Soc., 130, 16601-16610
    DOI: 10.1021/ja804071h
  • Polarz, S. Kuschel, A. (2008): Chemistry in confining reaction fields with special emphasis on nanoporous materialsChem. Eur. J., 14, 9816-9829
    DOI: 10.1002/chem.200800674
  • (2007): Structure–property–function relationships in nanoscale oxide sensors: a case study based on zinc oxideAdv. Funct. Mater, 17, 1385-1391
    DOI: 10.1002/adfm.200700139
  • (2007): Preparation of high-surface-area zinc oxide with ordered porosity, different pore sizes, and nanocrystalline wallsChem. Eur. J., 13, 592-597
    DOI: 10.1002/chem.200600428
  • Orlov, A. Roy, A. Lehmann, M. Driess, M. Polarz, S. (2007): Organometallics meet colloid chemistry: a case study in three phases based on molecular carbonyl precursors containing zinc and manganeseJ. Am. Chem. Soc, 129, 371-375
    DOI: 10.1021/ja0659626
  • Polarz, S. Regenspurger, R. Hartmann, J. (2007): Self-Assembly of Methylzinc Polyethylene Glycol Amphiphiles and Their Application to Materials SynthesisAngew. Chem. Int. Ed., 46,2426-2430
    DOI: 10.1002/anie.200602262
  • Polarz, S. Kuschel, A. (2006): Preparation of a periodically ordered mesoporous organosilica material using chiral building blocksAdv. Mater., 18, 1206-1209
    DOI: 10.1002/adma.200502647
  • Polarz, S. Strunk, J. Ischenko, V. van den Berg, M. W. E. Hinrichsen, O. Muhler, M. Driess, M. (2006): Über den Einfluss von Sauerstoffdefektstellen auf die katalytische Aktivität von ZinkoxidAngew. Chem., 118, 3031-3035
    DOI: 10.1002/ange.200503068
  • Van den Berg, M. W. E. Polarz, S. Tkachenko, O. P. Klementiev, K. V. Bandyopadhyay, M. Khodeir, L. Gies, H. Muhler, M. Grünert, W. (2006): Cu/ZnO aggregates in siliceous mesoporous matrices: Development of a new model methanol synthesis catalystJ. Catal., 241, 446-455
    DOI: 10.1016/j.jcat.2006.05.020
  • Ischenko, V. Polarz, S. Grote, D. Stavarache, V. Fink, K. Driess, M. (2005): Zinc Oxide Nanoparticles with DefectsAdv. Funct. Mater., 15, 1945-1954
    DOI: 10.1002/adfm.200500087
  • Polarz, S. Neues, F. van den Berg, M. W. Grunert, W. Khodeir, L. (2005): Mesosynthesis of ZnO-Silica Composites for Methanol NanocatalysisJ. Am. Chem. Soc., 127, 12028-34
    DOI: 10.1021/ja0516514
  • Polarz, S. Orlov, A. V. van den Berg, M. W. E. Driess, M. (2005): Molecular encoding at the nanoscale: From complex cubes to bimetallic oxidesAngew. Chem. Int. Edit., 44, 7892-7896
    DOI: 10.1002/anie.200501212
  • Polarz, S. Roy, A. Merz, M. Halm, S. Schroder, D. Schneider, L. Bacher, G. Kruis, F. E. Driess, M. (2005): Chemical vapor synthesis of size-selected zinc oxide nanoparticlesSmall, 1, 540-552
    DOI: 10.1002/smll.200400085
  • Schröder, D. Schwarz, H. Polarz, S. Driess, M. (2005): Consecutive fragmentations of the cubane-like zinc cluster [CH 3 Zn (OiC 3 H 7)] 4 upon electron ionizationPhys. Chem. Chem. Phys., 7, 1049-1053
  • Groenewolt, M. Antonietti, M. Polarz, S. (2004): Mixed micellar phases of nonmiscible surfactants: mesoporous silica with bimodal pore size distribution via the nanocasting processLangmuir, 20, 7811-7819
    DOI: 10.1021/la049147k
  • Roy, A. Polarz, S. Rabe, S. Rellinghaus, B. Zahres, H. Kruis, F. E. Driess, M. (2004): First preparation of nanocrystalline zinc silicate by chemical vapor synthesis using an organometallic single-source precursorChem. Eur. J., 10, 1565-1575
    DOI: 10.1002/chem.200305397
  • Dag, O. Soten, I. Celik, O. Polarz, S. Coombs, N. Ozin, G. A. (2003): Solventless Acid‐Free Synthesis of Mesostructured Titania: Nanovessels for Metal Complexes and Metal NanoclustersAdv. Funct. Mater., 13, 30-3
    DOI: 10.1002/adfm.200390001
  • Hornebecq, V. Mastai, Y. Antonietti, M. Polarz, S. (2003): Redox Behavior of Nanostructured Molybdenum Oxide-Mesoporous Silica Hybrid MaterialsChem. Mater., 15, 3586-3593
    DOI: 10.1021/cm0210492
  • Thomas, A. Polarz, S. Antonietti, M. (2003): Influence of spatial restrictions on equilibrium reactions: a case study about the excimer formation of pyreneJ. Phys. Chem. B, 107, 5081-5087
    DOI: 10.1021/jp026587g
  • Mastai, Y. Polarz, S. Antonietti, M. (2002): Silica-carbon nanocomposites: a new concept for the design of solar absorbersAdv. Funct. Mater., 12, 197-202
    DOI: Doi 10.1002/1616-3028(200203)12:3<197::Aid-Adfm197>3.0.Co;2-A
  • Polarz, S. Antonietti, M. (2002): Porous materials via nanocasting procedures: innovative materials and learning about soft-matter organizationChem. Comm., 2593-2604.
    DOI: 10.1039/B205708P
  • Polarz, S. Smarsly, B. Schattka, J. H. (2002): Hierachical porous carbon structures from cellulose acetate fibersChem. Mater., 14, 2940-2945
    DOI: 10.1021/cm011271r
  • Polarz, S. Smarsly, B. (2002): Nanoporous materialsJ Nanosci Nanotechnol, 2, 581-612
  • Bronstein, L. M. Polarz, S. Smarsly, B. Antonietti, M. (2001): Sub-Nanometer Noble-Metal Paricle Host Synthesis in Porous Silica MonolithsAdv. Mater., 13, 1333-1336
  • Han, B. H. Polarz, S. Antonietti, M. (2001): Cyclodextrin-based porous silica materials as in situ chemical “Nanoreactors” for the preparation of variable Metal− Silica hybridsChem. Mater., 13, 11, 3915-3919
    DOI: 10.1021/cm0110425
  • Polarz, S. Smarsly, B. Antonietti, M. (2001): Colloidal organization and clusters : self-assembly of polyoxometalate-surfacant complexes towards three-dimensional organized structuresChem. Phys. Chem., 2, 457-461
    DOI: 10.1002/1439-7641(20010716)2:7<457::AID-CPHC457>3.0.CO;2-#
  • Polarz, S. Smarsly, B. Bronstein, L. Antonietti, M. (2001): From cyclodextrin assemblies to porous materials by silica templatingAngew. Chem. Int. Ed. Engl., 40, 4417-4421
    DOI: 10.1002/1521-3773(20011203)40:23<4417::aid-anie4417>;2-p
  • Smarsly, B. Polarz, S. Antonietti, M. (2001): Preparation of Porous Silica Materials via Sol-Gel Nanocasting of Nonionic Surfactants : A Mechanistic Study on the Self-Aggregation of Amphiphiles for the Precise Prediction of the Mesopore SizeJ. Phys. Chem. B,105,10473-10483
    DOI: 10.1021/jp011905h
  • Polarz, S. Smarsly, B. Goltner, C. Antonietti, M. (2000): The Interplay of Colloidal Organization and Oxo‐Cluster Chemistry: Polyoxometalate–Silica Hybrids—Materials with a Nanochemical FunctionAdv. Mater., 12, 1503-1507
  • Achim Müller, Sebastian Polarz, Samar K. Das, Erich Krickemeyer, Hartmut Bögg, Marc Schmidtmann, Björn Hauptfleisch (1999): „Open and Shut”︁ für Gäste in Molybdän‐Sauerstoff‐Riesenkugeln, ‐körben und ‐rädern mit dem Pentagon als gemeinsamem StrukturelementAngew. Chem., 111, 3439-3443


  • Polarz, S., Kunkel, M., Donner, A., Schlotter, M. (2018): Added-Value SurfactantsChem. Eur. J., 24, 18842-18856
    DOI: 10.1002/chem.201802279
  • Polarz, S. (2011): Shape Matters: Anisotropy of the Morphology of Inorganic Colloidal Particles - Synthesis and FunctionAdv. Funct. Mater., 21, 3214-3230
    DOI: 10.1002/adfm.201101205


  • Polarz, S. (2004): Nanocasting Strategies and Porous MaterialsEncyclopedia of Supramolecular Chemistry
    DOI: 10.1081/E-ESMC 120019195


  • (2001): Konzepte der Nanochemie auf der Basis von porösen Materialien